Phase Separation
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Index   Experiments   Theory   Simulation   Drops   Conclusions
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Experimental Results

Sequence of Images

Movie: Critical phase separation (.avi file, 2 MB)

Analyzing the morphology of a typical critical binary liquid mixture as it phase separates, we observe the appearance of bicontinuous structures (see pictures on the left). The mean size L (in micron) of these microdomains grows linearly in time, with a growth rate of about 80 µm/s and 200 µm/s, depending on whether the morphology of the system is composed of isolated drops or interconnected domains, respectively. This clearly indicates that convection, and not diffusion, is the mechanism driving phase separation.

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One Drop Similar results are obtained studying the phase separation of off-critical liquid mixtures, although in this case we observe the formation of isolated drops instead of interconnected domains. Following the motion of individual droplets (see picture on the right), we see that they move very rapidly, with speeds exceeding 200 micron per seconds, confirming that convection is the dominant transport mechanism.

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Index   Experiments   Theory   Simulation   Drops   Conclusions
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By: Roberto Mauri, Reuel Shinnar, Rajan Gupta,
Last modified: 10 January 1999